XVIth International Workshop on Quantum Systems in Chemistry and Physics 

Abstract 
Laser ElectronGammaNuclear Spectroscopy of Diatomic and Multiatomic Molecules 
Svetlana V. Malinovskaya,^{1} and Andrey A. Svinarenko^{2}
^{1}Department of Chemistry, Odessa University, Odessa9, Ukraine
^{2}Department of Mathematics, Odessa University, Odessa9, Ukraine 
An important class of problems connected with modelling the cooperative laserelectrongammanuclear phenomena in diatomic and multiatomic molecules [1,2] is now of a great interest. It includes a calculation of the probabilities and energies of the mixed gammanuclear and optical quantum transitions in molecules, intensities of the complicated gammatransitions due to the changing of the molecular excited states because of the gamma nuclear transition. We present a consistent, quantum approach to calculation of the probabilities of the different cooperative laser electrongammanuclear processes in different molecules [2] (including the set of electron or vibrationrotational satellites of the gammanuclear spectrum). The calculation results for the electrongammanuclear transition probabilities in the diatomic (the nucleus 127I with E=203keV in molecule of H^{127}I) and vibrationnuclear transition probabilities for some threeatomic XY_{2}, fiveatomic XY_{4} molecules are given. In particular, we present the results of calculation for the vibrationnuclear transition probabilities in a case of the emission and absorption spectrum of nucleus 188Os (E=155 keV) in the molecule of OsO_{4} and nucleus 191Ir (E=82 keV) in the molecule IrO_{4}.
References:
[1]. V.S.Letokhov, V.Minogin, JETP. 69, 1369 (1975); A.Glushkov, L.Ivanov, Phys.Lett.A 170, 33 (1992); A.Glushkov, L.N.Ivanov, V.S.Letokhov, Preprint of ISAN N AS4, MoscowTroitsk, (1991);
[2]. A.Glushkov, S.Malinovskaya, O.Khetselius, Europ.Phys.Journ. T160, 195 (2009); Molec.Phys.(UK) 108, 1257 (2008); Int.J. Quant. Chem. 104, 496 (2005); Frontiers in Quantum Systems in Chem. and Phys. (Springer) 18, 523 (2008).


